GLASS & CERAMICS INDUSTRY

Glass industry
The major areas where energy conservation can be thought of in a glass industry are
  • Raw material section
  • Melting furnace
  • Auxiliaries
Raw Material Section

Beneficiation

Silica sand is the basic raw material for the glass industry. The quality of silica sand available in India is poor which especially contains high iron oxide and needs beneficiation. The beneficiation is basically washing with water which reduces contaminants to acceptable limits. The optimum iron oxide (Fe2O3) content is 0.03 to 0.08%. We do not have organized sectors in our country beneficiating the sand at source and supplying to the industry. Many of the glass manufacturing units have sand washing plants in the factory itself. They transport about 10 to 20% of unwanted material which is rejected in processing at the manufacturing facility. A captive sand washing plant should be designed for installation at the sand mine either individually or collectively by a number of companies. This would result in conservation of energy in transporting.

Hence the high capacity glass factories over 200 TPD can individually or collectively consider installing captive sand washing plants at or close to sand mines.

Drying Typically, natural drying (solar drying) is carried out after washing to minimise the moisture. The allowable moisture in sand is 3 to 4%.

Melting Aids Calumite which is processed blast furnace slag accelerates melting. Hence calumite should be introduced in the raw batch composition.

Grain size Both coarse grains and very fine grains should be eliminated for better thermal performance.

Normally all sand should be between 30 and 80 mesh i.e., the grain size being between 500 and 180 microns.

There should be no grain coarser than 20 mesh or finer than 100 mesh. Hence the acceptable grain size is between + 100 to - 20 mesh size.

Raw material mix

Generally a mix of fresh raw material (batch) and cullets (recycled glass) is used as raw material input to the furnace. Higher the percentage of cullets, better will be the fuel efficiency. Another advantage is that the cullets are cheaper. Fuel efficiency improvement to the tune of 10 to 20% is possible by increasing the cullet percentage to 90%. However there is a practical limitation on cullet usage beyond 90%, due to retardation of movement of raw material at filling point.

Pre-heating of raw material

Pre-heating of raw material is in initial stages of development in developed countries. The pre-heating is carried out by any of the following methods.
  • Direct heating in case of cullets
  • In-direct heating in case of fresh raw material
The pre-heating is feasible where large volumes of cullets are handled.

Melting furnace

Melting furnace is the major consumer of energy in glass industry. The energy conservation aspects to be considered in design stage in melting furnace are highlighted in the following sections.

Size of the furnace

Size of the furnace determines the operating efficiency and the overall profitability of the company. The specific fuel consumption varies with the size of the furnace. Typical data is shown below


Size Fuel Glass ratio
Upto 300 TPD 1:10
Upto 100 TPD 1:5


The suggested minimum size of furnaces are to have economy of scale as follows

Type of Glass Size of the plant
Container Glass 200 - 250 TPD
Float Glass 500 TPD


Campaign life

Campaign life of a melting furnace in glass industry decides the overall economics of the plant. Higher the campaign life, better will be the economics. The campaign life in early 1950's was only 2 to 3 years and has been increased to 6 to 8 years due to development in the refractory material and technology. Few new plants have incorporated good design features to achieve the campaign life of 10 years. The range varies from 2 years in high value optical glass electric melters and from 10 to 12 years in large float glass furnaces. Hence it is prudent to incorporate appropriate design features to improve the campaign life in all types of glass melting furnaces.

Refractory material

Selection of type of refractory material and type of joints play a major role in the life of the furnace and energy consumption.
The suggested refractory materials are as follows

Identification Type of refractory material
Glass contact area AZS Electrocast with Zirconia
Super structure AZS Zircon and Silica
Crown Super Silica


The joints have to be perfect and the gaps should be minimum while constructing the furnace.

Oxy fuel burners

In the present context of environmental regulations, oxy-fuel burner have an advantage of reduced Nox emissions. In some developed countries oxy-fuel burners are established and yielding good results from environmental point of view. In our country, use of oxy-fuel burners are not economical at the present costs. However from environmental point of view, the incorporation of oxy fuel firing may have to be resorted to confirm to the strict environmental regulations in near future. Energy conservation by oxyfuel is still a grey area.

Sealed in burner blocks

The underport oil firing system also plays a role in fuel consumption. Conventionally an opening around the burner is provided to allow induced cold air to cool the burner tip. This cold air entry consumes higher heat energy than hot air through regenerator. Firing systems should be designed to seal the burner in the burner block preventing any induced cold air. Now-a-days "Sealed in burner blocks" are available in the market and can save 3 to 5% of energy

Hence installation of a sealed in burner blocks for burners should be considered for maximum energy saving at design stage.

Insulation

Selection of right type of insulation reduces fuel consumption at furnace enormously. In 1935, the overall efficiency of furnace was about 19% and the present efficiency is more than 50%. The major reason for their improvement is the development of better refractory and insulating materials. The insulating material has to be compatible with refractory material.

Different areas of the furnace should be insulated with specific insulating materials compatible with refractory materials.

Pre-heating of furnace during start up

Present trend during furnace start up is to pre-heat the air up to 8000C and inject directly into the furnace. After 800°C, direct heating with burners is practiced. The rate of heat has also been increased from 1°C/hr to 5 to 10oC/hr. With this approach the pre-heating time would come down from 20 days to 6 days. This reduces the over-all fuel consumption in pre-heating. All joints have to be thoroughly sealed after pre-heating of furnace.
Waste heat recovery system

The typical waste heat system at the furnace is
Furnace exhaust Regenerator or Recuperator

Raw material
Chimney pre-heating

Regenerators and recuperators are used to recover waste heat in the melting furnaces. Regenerators are relatively more efficient when compared to recuperators.

Regenerator The checkered work in modern regenerator is of Magnesite brick on top and High alumina at the bottom.

Recuperator For low capacity furnaces (10T/day) the recuperator can be of metallic/refractory material. The metallic recuperators have a temperature limit (Max. 900 to 1000°C). The refractory recuperators can with stand high temperatures but the leakages should be taken care of.

Instrumentation system

The flue gas analysis is essential to sustain efficient combustion in furnaces. An on-line oxygen analyser can be installed to check oxygen and fine tune the air fuel ratio to achieve optimum combustion efficiency. Hence installation of on-line oxygen analyser for melting furnace is suggested.

Fans and blowers

The flux line cooling and throat cooling fans can be fitted with variable speed drives (VSDs), preferably variable frequency drives (VFDs). The advantage of these drives is, depending on the capacity requirement at the furnace, the capacity of fans can be varied automatically and achieve optimum efficiency.

Hence install correct size fans for flux line cooling and throat cooling fitted with variable frequency drives.

Lehrs

Generally, electrically heated annealing lehrs are used to carry out annealing of glass products.

The following points are to be considered while selecting/operating lehrs
  • Explore the possibility of thermic fluid heated lehrs instead of electrically heated lehr.
  • Install atleast two standard size lehrs matching the different product size. Operate the lehr, which can allow little gap between the components and the lehr body to minimise energy consumption.
  • Recirculate hot air from central zone to side zones should be practised.
 

Introduction

Ceramics Industry

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